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To equip Spidey with Venom's powerful suit, enter the room where the Lizard's key may be found at the end of the game. Then, move to the bottom-right of the room, wait until you are covered in slime and then hit DOWN and JUMP at the same time. When you leap out of the goo, you'll be wearing Venom's suit.
If playing the retro-hip Spider-Man is not enough of a flashback for you, then get the key from Electro's key room and drop down the left-hand side of the screen where the Game Gear icon is located. When Peter's room comes into view, press Button 2 to launch into a game of classic Pac-Man!